Enantioselective Heck Arylations of Endocyclic Enelactams Using N,N Ligands

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  • Presentation type: Sessão Coordenada PG - Pós Graduando
  • Track: Química Orgânica - ORG
  • Keywords: Arylation; enantioselective synthesis; Enelactams; Heck reaction; N,N Ligands;

Authors:

  • 1 Universidade Estadual de Campinas
  • 2 Universidade de São Paulo

Enantioselective Heck Arylations of Endocyclic Enelactams Using N,N Ligands

Ingredy Bastos Braga

Universidade Estadual de Campinas

Abstract

In this work, we developed a new method for the enantioselective arylation of endocyclic enelactams via Heck reactions. The Heck products can be obtained in good yields and enantiomeric excesses up to 90%. The reaction mechanism was also investigated via DFT in silico studies.

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