Structural and optical characterization of rare earth-doped Metal-Organic Framework towards RE3+-luminescent vitrified MOFs

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Abstract

Metal-Organic Framework glasses (agMOFs) emerge as a novel class of glass that overcomes the poor processability of crystalline MOFs. Although rare earth (RE3+)-containing MOFs are widely studied for their optical and magnetic properties, no RE3+-doped agMOF has been reported to date. This study addresses this gap by synthesizing and characterizing several novel RE3+-doped (Eu3+, Sc3+ Yb3+/Er3+) zeolitic imidazolate frameworks (ZIFs), evaluating the impacts of doping on their thermal, optical, and structural properties to develop novel agMOFs:RE3+ matrices.

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Programme
19:40 to 21:00 on 09/15/2026
Room 4 and 5
Institutions
  • 1 Chemistry Institute of São Carlos (IQSC), University of São Paulo (USP)
  • 2 São Carlos Institute of Physics, IFSC - USP
  • 3 Instituto de Química de São Carlos, Universidade de São Paulo (IQSC-USP), Departamento de Química e Física Molecular
Track
  • TL04 - Rare Earth Chemistry and Applications
Keywords
optical-structural probe
nuclear magnetic resonance
hybrid glass