Assignment of absolute configuration of 6-deoxyclitoriacetal isolated from Clitoria fairchildiana by calculated CD spectra

Vol 9, 2023 - 167277
Poster
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Abstract

Despite the assignment of 6-deoxyclitoriacetal from C. farchildiana was (6aR,12aR), based on comparison with the optical rotation of other 12a-hydroxyrotenoids, the absolute configuration, investigated through calculated and experimental CD, indicated it is opposite to that previously established, (6aS,12aS).

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Institutions
  • 1 Universidade Federal da Bahia
  • 2 Universidade Federal de Alagoas
Track
  • 1. Biodiversity and Natural Products
Keywords
calculated CD; Clitoria farchildiana; 6-deoxyclitoriacetal; absolute configuration